I have many different colors of acrylic paint that I've collected over the years. Almost all the paints I use are Artists' grade paint to ensure they will mix as expected and to ensure my artwork is archival. The only exceptions are when I use metallic paints for abstract works.
The color pallet I use for acrylic is a limited pallet. I do some abstracts fairly large, so it was important that I could get good mixtures from the least amount of colors - this way I could buy larger containers of paint at a lower cost. It does require more mixing when I paint, but I'm happy with the results. I also required colors that are transparent because I paint with glazes often.
When deciding, I chose what Golden recommended in their color mixing guide. You can read the explanation at this link: http://www.goldenpaints.com/artist/mixguide.php, but here are the colors suggested.
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